Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Oxygen → 4-Nitrobenzanilide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Oxygen | HCID 977 | — |
| 반응물 | Benzamide | HCID 2331 | — |
| 반응물 | Tetramethylammonium hydroxide | HCID 60966 | — |
| 반응물 | 4'-Nitrobenzanilide | HCID 76930 | — |
| 용매 | Nitrobenzene | HCID 7416 | — |
| 용매 | Acetonitrile methanol | HCID 21959252 | — |
| 생성물 | 4-Nitrobenzanilide | HCID 77003 | 20% |
반응 단계
Benzamide (10 mmole) and 10 mmole of tetramethylammonium hydroxide in 10 g of nitrobenzene was stirred at 75°-80° C./56-63 psi (3.9 -4.4 kg/cm2) oxygen for 12 hours. Methanol/acetonitrile (4:6) (10 mL)solution was then added to homogenize the solution. A weighted aliquot was sampled for HPLC assay and revealed 20% yield of 4-nitrobenzanilide, i.e.,N-(4-nitrophenyl)benzamide. No azoxybenzene was detected.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05331099 |
| 출처 데이터셋 | uspto-grants-1994_07 |
| ORD ID | ord-4df96f44d270495fb04426143db9c0b9 |
| 출처 메모 | uspto-grants-1994_07 |