Dibenzosuberone → HCID 53961708, 화합물

HRID 1729517노트

반응식

HRID 1729517 반응식
[CH2:1]1[C:16]2[C:11](=[CH:12][CH:13]=[CH:14][CH:15]=2)[C:9](=O)[C:8]2[C:3](=[CH:4][CH:5]=[CH:6][CH:7]=2)[CH2:2]1.[CH2:17]([O:19]C=C[Li])[CH3:18]>C1COCC1>[CH:4]1[C:3]2[C:2]3[CH2:1][CH2:16][CH:15]=[CH:14][C:13]=3[CH:12]=[CH:11][C:9](=[CH:18][CH:17]=[O:19])[C:8]=2[CH:7]=[CH:6][CH:5]=1

참가 물질

4

반응물 2

HCID 14589DibenzosuberoneHCID 178506908HCID 178506908, 화합물

생성물 1

HCID 53961708HCID 53961708, 화합물

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매

실험 절차

Dibenzosuberone (5.3 g, 0.026 mol) was reacted with 1-ethoxy-2-lithio ethylene in anhydrous THF in the manner of Preparation 1 to yield present title product as a yellow oily solid, 2.86 g (48% ).

출처 및 근거

ORD 기록
ord-0d9923afeaba431fbe1b98233b0cb58e
출처 데이터셋
uspto-grants-1994_07
특허 번호
US05332857

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