Pyridine → tert-Butyl 3-[(chlorocarbonyl)oxy]propaneperoxoate

HRID 1730106노트

반응식

HRID 1730106 반응식
CCCCC.[C:6](Cl)([Cl:8])=[O:7].[C:10]([O:14][O:15][C:16](=[O:20])[CH2:17][CH2:18][OH:19])([CH3:13])([CH3:12])[CH3:11].N1C=CC=CC=1>C(OCC)C>[Cl:8][C:6]([O:19][CH2:18][CH2:17][C:16]([O:15][O:14][C:10]([CH3:13])([CH3:11])[CH3:12])=[O:20])=[O:7]

참가 물질

6

반응물 4

HCID 1049PyridineHCID 6371PhosgeneHCID 8003PentaneHCID 20371803tert-Butyl 3-hydroxypropaneperoxoate

생성물 1

HCID 20559661tert-Butyl 3-[(chlorocarbonyl)oxy]propaneperoxoate

시약·촉매·용매 1

HCID 3283Diethyl Ether용매

실험 절차

To 75 ml. of pentane at -10° to +5° C was added 39.6g. of phosgene. To this mixture was added a mixture of t-butyl-3-hydroxyperoxypropionate (38g. 0.2 moles of 85% pure products) and pyridine (15.8g. 0.2 moles) in diethyl ether over a period of one hour.

후처리

  1. additionTo this mixture was added

출처 및 근거

ORD 기록
ord-c79b6488d4a1408e93f11e8622c3c1ca
출처 데이터셋
uspto-grants-1976_11
특허 번호
US03991109

반응 노트

불러오는 중…