HCID 178448085, 화합물 → p-Menthan-7-ol

HRID 1730611노트

반응식

HRID 1730611 반응식
[CH:1]([C@H:4]1[CH2:9][CH2:8][C@H:7]([CH2:10][OH:11])[CH2:6][CH2:5]1)([CH3:3])[CH3:2]>[Ru].COCCOC>[CH:1]([CH:4]1[CH2:9][CH2:8][CH:7]([CH2:10][OH:11])[CH2:6][CH2:5]1)([CH3:3])[CH3:2]

참가 물질

4

반응물 1

HCID 178448085HCID 178448085, 화합물

생성물 1

HCID 83763p-Menthan-7-ol

시약·촉매·용매 2

HCID 23950Ruthenium촉매HCID 80711,2-Dimethoxyethane용매

실험 절차

A mixture of 200 g of cuminic aldehyde, 200 g of 1,2-dimethoxy-ethane and 6 g of ruthenium -- 5% on charcoal; Doduco Chemie Werk, Sinsheim Elsenz, West Germany -- were heated in a stainless steel autoclave at 130° and at a pressure of 100 atm, for 25 h. The obtained reaction mixture was then filtered and subjected to a fractional distillation to yield 176 g (85%) of a 70 : 30 (parts by weight) mixture of cis and trans-4-isopropyl-cyclohexylmethanol.

후처리

  1. customThe obtained reaction mixture
  2. filtrationwas then filtered
  3. distillationsubjected to a fractional distillation
  4. customto yield

출처 및 근거

ORD 기록
ord-4fb9b8670f2d47448a58614245f5c395
출처 데이터셋
uspto-grants-1976_11
특허 번호
US03993604

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