4-Iodoaniline → HCID 14099777, 화합물

HRID 1732048노트

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HRID 1732048 반응식
[C:1]([C:3]1[CH:12]=[CH:11][C:6]([C:7](=[O:10])[CH2:8]I)=[CH:5][CH:4]=1)#[N:2].[I:13][C:14]1[CH:20]=[CH:19][C:17]([NH2:18])=[CH:16][CH:15]=1>C(O)C>[I:13][C:14]1[CH:20]=[CH:19][C:17]([NH:18][CH2:8][C:7]([C:6]2[CH:11]=[CH:12][C:3]([C:1]#[N:2])=[CH:4][CH:5]=2)=[O:10])=[CH:16][CH:15]=1

참가 물질

4

반응물 2

HCID 108934-IodoanilineHCID 143737Benzonitrile, 4-(iodoacetyl)-

생성물 1

HCID 14099777HCID 14099777, 화합물

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

p-Cyanophenacyl iodide (18.0 g, 0.08 mole) was combined with p-iodoaniline (35.2 g, 0.16 mole) in 32.1 g of absolute ethanol and stirred 16 hours. Precipitated title product was recovered by filtration and repulped in 400 ml ether: 42.4 g; m.p. 160°-165°; ms 362, 232, 219.

후처리

  1. customPrecipitated title product
  2. filtrationwas recovered by filtration

출처 및 근거

ORD 기록
ord-d19b9e0065484701ad8165e8c6bbf597
출처 데이터셋
uspto-grants-1986_11
특허 번호
US04624958

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