Thionyl Chloride → HCID 20304079, 화합물

HRID 1732628노트

반응식

HRID 1732628 반응식
[CH:1]1([C:7]2[CH:12]=[CH:11][C:10]([CH:13]([C:15]3[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=3)O)=[CH:9][CH:8]=2)[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.S(Cl)([Cl:23])=O>C1C=CC=CC=1>[CH:1]1([C:7]2[CH:12]=[CH:11][C:10]([CH:13]([C:15]3[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=3)[Cl:23])=[CH:9][CH:8]=2)[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1

참가 물질

4

반응물 2

HCID 24386Thionyl ChlorideHCID 12470613HCID 12470613, 화합물

생성물 1

HCID 20304079HCID 20304079, 화합물수율 97%

시약·촉매·용매 1

HCID 241Benzene용매

반응 조건

온도
70 °C

실험 절차

76 g (0.286 mol) of 4-cyclohexylphenylphenylcarbinol are introduced in portions into a mixture of 143 ml (2 mols) of thionyl chloride and 200 ml of benzene at 70° C. The reaction mixture is heated to 70° C. for 15 hours and then evaporated. The oil which remains is stirred with petroleum ether, whereupon it solidifies to a crystal sludge. 79 g (96% of theory) of 4-cyclohexylphenyl-phenylchloromethane of melting point 75° C. are obtained. ##STR7##

후처리

  1. customevaporated

출처 및 근거

ORD 기록
ord-cc6489ae926a45a1a6cd8b9ef800233f
출처 데이터셋
uspto-grants-1980_12
특허 번호
US04238498

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