Aniline → 2-Butylmercaptoaniline

HRID 1732822

반응식

[N+:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[SH:10])([O-])=O.N[C:12]1[CH:17]=CC=[CH:14][CH:13]=1.C(N1CCCC1=O)O.ClCC(Cl)=O>>[CH2:17]([S:10][C:5]1[CH:6]=[CH:7][CH:8]=[CH:9][C:4]=1[NH2:1])[CH2:12][CH2:13][CH3:14]

참가 물질

반응물 4

HCID 6115Aniline

HCID 6577Chloroacetyl chloride

HCID 21002o-Nitrobenzenethiol

HCID 849112-Pyrrolidinone, 1-(hydroxymethyl)-

생성물 1

HCID 103299602-Butylmercaptoaniline

실험 절차

2-Butylmercaptoaniline was prepared from -2-nitrothiophenol by a two-step reaction sequence consisting of alkylation followed by reduction corresponding to the procedure described in Example 4. The aniline then was condensed with N-methylolpyrrolidone, followed by reaction with chloroacetyl chloride to yield the desired product.

후처리

customby a two-step reaction sequence

출처 및 근거

ORD 기록: ord-9bb7ea5ee3214d5ca67c785aa455bc90
출처 데이터셋: uspto-grants-1980_12
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04239688

연결된 노트

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