2-Cyclopenten-1-one, 4-hydroxy-3-methyl-2-(2-propen-1-yl)- → alpha-Cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(-2-(isopropoxyimino)propyl)cyclopropanecarboxylat

참여 물질

역할	이름	HCID	투입량
반응물	2-Cyclopenten-1-one, 4-hydroxy-3-methyl-2-(2-propen-1-yl)-	HCID 11083	—
반응물	Benzenemethanol, 2,6-dichloro-	HCID 27156	—
반응물	N-(Hydroxymethyl)-3,4,5,6-tetrahydrophthalimide	HCID 78597	—
반응물	3-Phenoxy-alpha-ethynylbenzylalcohol	HCID 12919092	—
반응물	alpha-cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(neopentoxyimino)propyl)cyclopropanecarboxylate	HCID 53762777	—
반응물	3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(isobutoxyimino)propyl)cyclopropanecarboxylate	HCID 54499472	—
반응물	alpha-cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(cyclopropylmethoxyimino)propyl)cyclopropanecarboxylate	HCID 86737170	—
반응물	alpha-cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(cyclobutylmethoxyimino)propyl)cyclopropanecarboxylate	HCID 86737171	—
생성물	alpha-Cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(-2-(isopropoxyimino)propyl)cyclopropanecarboxylat	HCID 53742917	—

반응 단계

Following procedures similar to Embodiment II above: α-cyano -3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(neopentoxyimino)propyl)cyclopropanecarboxylate, 3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(isobutoxyimino)propyl)cyclopropanecarboxylate, α-cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(cyclopropylmethoxyimino)propyl)cyclopropanecarboxylate, α-cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(cyclobutylmethoxyimino)propyl)cyclopropanecarboxylate are prepared as well as the corresponding esters in the racemic and (1R,trans) form and similar esters with other alcohols: α-ethynyl-3-phenoxybenzyl alcohol, 3,4,5,6-tetrahydrophthalimidomethyl alcohol, 2,6-dichlorobenzyl alcohol, 2-chloro-4-phenyl-2-butenl-o1 and allethrolone.

출처 및 근거

DOI	10.6084/m9.figshare.5104873.v1
특허 번호	US04242521
출처 데이터셋	uspto-grants-1980_12
ORD ID	ord-ee2702e9dd3e44b1b8632b1eefac668c
출처 메모	uspto-grants-1980_12