Ethanol → 2-[[(4-Ethenylphenyl)methoxy]methyl]-2-(hydroxymethyl)butyl ethyl carbonate

반응식

[CH2:1]([C:3]1([CH2:10][O:11][CH2:12][C:13]2[CH:18]=[CH:17][C:16]([CH:19]=[CH2:20])=[CH:15][CH:14]=2)[CH2:8][O:7][C:6](=[O:9])[O:5][CH2:4]1)[CH3:2].[C:21]1(C)C=CC(S(O)(=O)=O)=CC=1.[CH2:32]([OH:34])C>>[CH2:1]([C:3]([CH2:10][O:11][CH2:12][C:13]1[CH:14]=[CH:15][C:16]([CH:19]=[CH2:20])=[CH:17][CH:18]=1)([CH2:8][O:7][C:6]([O:5][CH2:4][CH3:21])=[O:9])[CH2:32][OH:34])[CH3:2]

참가 물질

반응물 3

HCID 702Ethanol

HCID 6101p-Toluenesulfonic acid

HCID 19373498HCID 19373498, 화합물

생성물 1

HCID 194384272-[[(4-Ethenylphenyl)methoxy]methyl]-2-(hydroxymethyl)butyl ethyl carbonate

실험 절차

Analogous to Example 1, the title compound was synthesized using 13.8 g of 5-ethyl-5-(4-vinylbenzyloxy) methyl-2-oxo-1,3-dioxane, 4,6 g of ethanol and 0.2 g of p-toluenesulfonic acid.

출처 및 근거

ORD 기록: ord-6d929e588bc64dc1b9dcc1b248913753
출처 데이터셋: uspto-grants-1996_07
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05534647

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