Ammonia → Allyl 4-allyloxy-3-aminobenzoate

HRID 1736358노트

반응식

HRID 1736358 반응식
[CH2:1]([O:4][C:5]1[CH:16]=[CH:15][C:8]([C:9]([O:11][CH2:12][CH:13]=[CH2:14])=[O:10])=[CH:7][C:6]=1[N+:17]([O-])=O)[CH:2]=[CH2:3].C(OC1C=C([N+]([O-])=O)C=CC=1C(OCC=C)=O)C=C.N>CO>[CH2:1]([O:4][C:5]1[CH:16]=[CH:15][C:8]([C:9]([O:11][CH2:12][CH:13]=[CH2:14])=[O:10])=[CH:7][C:6]=1[NH2:17])[CH:2]=[CH2:3]

참가 물질

5

반응물 3

HCID 222AmmoniaHCID 11666115HCID 11666115, 화합물HCID 19432496HCID 19432496, 화합물

생성물 1

HCID 19432523Allyl 4-allyloxy-3-aminobenzoate

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

The above nitro compound was reduced by the method described in example 1, for the reduction of allyl 2-allyloxy-4-nitrobenzoate, except that the solvent was methanol, and using an aqueous solution of ammonia in place of sodium bicarbonate in the work-up, to give allyl 4-allyloxy-3-aminobenzoate.

출처 및 근거

ORD 기록
ord-4b065fbabcf24293b417dcacb350f0a1
출처 데이터셋
uspto-grants-1996_07
특허 번호
US05541178

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