tert-Butylacetic acid → HCID 178442262, 화합물

HRID 1737150노트

반응식

HRID 1737150 반응식
[CH:1]1[CH:2]=[CH:3][C:4]2[C:11](=[O:12])[C:10]([OH:13])=[CH:9][C:7](=[O:8])[C:5]=2[CH:6]=1.[CH3:14][C:15]([CH3:21])([CH3:20])[CH2:16]C(O)=O.S(O[O-])([O-])(=O)=O.[NH4+].[NH4+]>C(#N)C.O.[N+]([O-])([O-])=O.[Ag+]>[CH3:14][C:15]([CH3:21])([CH3:20])[CH2:16][C:9]1[C:7](=[O:8])[C:5]2[C:4]([C:11](=[O:12])[C:10]=1[OH:13])=[CH:3][CH:2]=[CH:1][CH:6]=2

참가 물질

7

반응물 3

HCID 14057tert-Butylacetic acidHCID 9855511Ammonium peroxysulphateHCID 178516607HCID 178516607, 화합물

생성물 1

HCID 178442262HCID 178442262, 화합물

시약·촉매·용매 3

HCID 24470Silver Nitrate촉매HCID 962Water용매2회HCID 6342Acetonitrile용매

실험 절차

This compound was prepared by the general methods as described in Examples 1 to 15. Lawsone (0.15 g), 3,3-dimethylbutyric acid (0.15 g), and silver nitrate (0.15 g) were heated in a mixture of acetonitrile (5 ml) and water (5 ml) at 60-65° C. A solution of ammonium peroxysulphate (0.3 g) in water (5 ml) was added dropwise and the mixture heated for 1 hour and then processed as for Example 3 to yield the title compound . The crude product was purified on a silica gel column using 20% diethyl ether in petroleum ether eluant and recrystallised from petroleum ether to yield 38 mg of the title compound.

후처리

  1. customThis compound was prepared by the general methods
  2. temperaturethe mixture heated for 1 hour

출처 및 근거

ORD 기록
ord-7b53e09bc124424688b926d1dac1b8a3
출처 데이터셋
uspto-grants-1999_10
특허 번호
US05962002

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