참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Methanol | HCID 887 | — |
| 반응물 | 1-Bromo-3-chloropropane | HCID 8006 | — |
| 반응물 | N,N-Dimethyl-N-decylamine | HCID 70711 | — |
| 용매 | Methyl t-butylether hexane | HCID 21982663 | — |
| 생성물 | (3-Chloropropyl)decyldimethylammonium bromide | HCID 85711137 | — |
반응 단계
Into a 1000 mL, round-bottomed flask equipped with air condensers and a magnetic stirring plate was charged N,N-dimethyldecylamine (200.0 grams, 1.08 moles), 1-bromo-3-chloropropane (170 grams, 1.08 moles) and methanol (200 mL). The reaction was maintained at 65° C. for 18 hours. Solvent was removed by rotary evaporation under reduced pressure and furthermore with high vacuum distillation to yield brown oil. The oil was placed in a beaker and stirred with hexane/t-butylmethylether 1:1 solution (400 mL) causing a white precipitate. The solids were collected by vacuum filtration. Solids were dried in a vacuum oven at 30° C. overnight. Yield 305.0 grams (0.089 moles, 82%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US05969090 |
|---|
| 출처 데이터셋 | uspto-grants-1999_10 |
|---|
| ORD ID | ord-d1033feccafd4fd0af23433b4b7180af |
|---|
| 출처 메모 | uspto-grants-1999_10 |
|---|
