Diisobutylaluminum hydride → 3-(2-Pyridyl)-2-propen-1-ol
반응식
CC(C[AlH]CC(C)C)C.[N:10]1[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=1/[CH:16]=[CH:17]/[C:18](OCC)=[O:19]>C1(C)C=CC=CC=1>[N:10]1[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=1/[CH:16]=[CH:17]/[CH2:18][OH:19]참가 물질
4
실험 절차
As in Example 3, Step 2, but using a 1.5M solution of DIBAL in toluene, the ester from Step 1 of the present example was converted to the title compound. The alcohol was chromatographed on silica using EtOAc/toluene (9:1) as eluent.
출처 및 근거
- ORD 기록
- ord-8c2846b9ad0c48d890b85d4f80be9722
- 출처 데이터셋
- uspto-grants-1994_08
- 특허 번호
- US05334597
반응 노트
불러오는 중…