Dibenzylphosphate → Silver(1+) dibenzyl phosphate

HRID 1742565노트

반응식

HRID 1742565 반응식
[P:1]([O-:19])([O:11][CH2:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)([O:3][CH2:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)=[O:2].C(=O)([O-])[O-].[Ag+2:24]>C(#N)C.O.[Al]>[P:1]([O-:19])([O:3][CH2:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)([O:11][CH2:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)=[O:2].[Ag+:24]

참가 물질

6

반응물 2

HCID 4193600DibenzylphosphateHCID 178418647HCID 178418647, 화합물

생성물 1

HCID 13248164Silver(1+) dibenzyl phosphate

시약·촉매·용매 3

HCID 962Water용매HCID 6342Acetonitrile용매HCID 5359268Aluminum용매

실험 절차

Dibenzyl phosphate (10 mmole, 2.78 g) is dissolved in a mixture of acetonitrile (20 ml) and water (10 ml). Silver carbonate (10 mmole, 2.76 g) is added, and the mixture is stirred at room temperature in the dark (wrapped in aluminum foil) for 2 hours. Excess of silver carbonate is removed by filtration. The solution is evaporated to dryness, and dried over P2O5 in the dark to constant weight (2 days). Yield of silver dibenzoyl phosphate is 3.61 g.

후처리

  1. customExcess of silver carbonate is removed by filtration
  2. customThe solution is evaporated to dryness
  3. dry with materialdried over P2O5 in the dark to constant weight (2 days)

출처 및 근거

ORD 기록
ord-15a98c1de96241289821676313a506a5
출처 데이터셋
uspto-grants-1994_08
특허 번호
US05340568

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