Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Acetic Acid → Adipic Acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Acetic Acid | HCID 176 | — |
| 반응물 | Nitric Acid | HCID 944 | — |
| 반응물 | Oxygen | HCID 977 | — |
| 반응물 | Cyclohexanone | HCID 7967 | — |
| 촉매 | Cobalt dinitrate | HCID 25000 | — |
| 촉매 | Manganese nitrate | HCID 61511 | — |
| 생성물 | Adipic Acid | HCID 196 | — |
반응 단계
A solution containing 25 mmol of cyclohexanone, 0.5 mmol of manganese(II) nitrate, 0.5 mmol of cobalt(II) nitrate and 1.5 mmol of nitric acid in 25 ml of acetic acid was stirred for 5 h at 40° C. in an oxygen atmosphere under ambient pressure. Subsequently, the acetic acid was distilled off. The residue was found to consist mainly of adipic acid with some glutaric acid and a small amount of unreacted starting material. The conversion of cyclo-hexanone was found to be 97.5%, the selectivity of the oxidation to adipic acid being 93.4%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07012155B2 |
| 출처 데이터셋 | uspto-grants-2006_03 |
| ORD ID | ord-ea8b88fa6ef14293914a9ca4eb3c2d0d |
| 출처 메모 | uspto-grants-2006_03 |