3-Methoxyphenol → HCID 9884225, 화합물

HRID 1744439노트

반응식

[CH3:1][O:2][C:3]1C=C(O)[CH:6]=[CH:7][CH:8]=1.[CH2:10]([O:12][C:13](=[O:28])[C:14]([C:26]#[N:27])=[CH:15][C:16]1[CH:21]=[C:20]([O:22][CH3:23])[CH:19]=[C:18]([O:24][CH3:25])[CH:17]=1)[CH3:11]>>[C:26]([C:14]1[C:13](=[O:28])[O:12][C:10]2[C:6]([C:15]=1[C:16]1[CH:21]=[C:20]([O:22][CH3:23])[CH:19]=[C:18]([O:24][CH3:25])[CH:17]=1)=[CH:7][CH:8]=[C:3]([O:2][CH3:1])[CH:11]=2)#[N:27]

참가 물질

반응물 2

HCID 90073-Methoxyphenol

HCID 2732672HCID 2732672, 화합물

생성물 1

HCID 9884225HCID 9884225, 화합물수율 4.2%

실험 절차

The title compound was prepared from 3-methoxyphenol and 2-cyano-3-(3,5-dimethoxy-phenyl)-acrylic acid ethyl ester by a procedure similar to that described for Example 1 in 4.2% yield. 1H NMR (CDCl3): 7.36 (d, J=9.0, 1H), 6.89-6.83 (m, 2H), 6.65-6.63 (m, 1H), 6.55-6.54 (m, 2H), 3.93 (s, 3H), 3.85 (s, 6H).

출처 및 근거

ORD 기록: ord-55b80db7c0ae4aa8a03d061ae330b8e5
출처 데이터셋: uspto-grants-2006_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07015328B2

반응 노트

불러오는 중…