Ceric ammonium nitrate → HCID 42598871, 화합물

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[OH:1][C:2]1[C:3]([CH3:20])=[C:4]2[C:9](=[C:10]([CH3:13])[C:11]=1[CH3:12])[O:8][C:7]([CH3:19])([C:14]([N:16]([CH3:18])[CH3:17])=[O:15])[CH2:6][CH2:5]2.[O:21]=[N+]([O-])[O-].[O-][N+](=O)[O-].[O-][N+](=O)[O-].[O-][N+](=O)[O-].[O-][N+](=O)[O-].[O-][N+](=O)[O-].[Ce+4].[NH4+].[NH4+]>>[OH:21][C:7]([CH3:19])([CH2:6][CH2:5][C:4]1[C:9](=[O:8])[C:10]([CH3:13])=[C:11]([CH3:12])[C:2](=[O:1])[C:3]=1[CH3:20])[C:14]([N:16]([CH3:18])[CH3:17])=[O:15]

참가 물질

반응물 2

HCID 180504Ceric ammonium nitrate

HCID 67263064HCID 67263064, 화합물

생성물 1

HCID 42598871HCID 42598871, 화합물수율 95.4%

실험 절차

Oxidation as described in protocol B, using 138.6 mg (0.50 mmol) of 6-hydroxy-N,N,2,5,7,8-hexamethylchroman-2-carboxamide and 560 mg CAN (1.02 mmol) yielded 139.9 mg of 2-hydroxy-N,N,2-trimethyl-4-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)butanamide as a yellow oil.

출처 및 근거

ORD 기록: ord-8107df0c262b49258cd25d4cd4fd6450
출처 데이터셋: uspto-grants-2015_10
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US09169196B2

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