Tetradecyl isocyanate → 3,4-Bis [[(tetradecylamino)carbonyl]oxy]nitrobenzene

반응식

[N+:1]([C:4]1[CH:5]=[C:6]([OH:11])[C:7](=[CH:9][CH:10]=1)[OH:8])([O-:3])=[O:2].[CH2:12]([N:26]=[C:27]=[O:28])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25]>>[CH2:12]([NH:26][C:27]([O:11][C:6]1[CH:5]=[C:4]([N+:1]([O-:3])=[O:2])[CH:10]=[CH:9][C:7]=1[O:8][C:27]([NH:26][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])=[O:28])=[O:28])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25]

참가 물질

반응물 2

HCID 3485710Tetradecyl isocyanate

HCID 35051094-Nitrocatechol

생성물 1

HCID 545517223,4-Bis [[(tetradecylamino)carbonyl]oxy]nitrobenzene

실험 절차

Using this procedure, the reaction of 4-nitrocatechol with tetradecyl isocyanate gave 3,4-bis [[(tetradecylamino)carbonyl]oxy]nitrobenzene (mp 100°-104°). The structure was confirmed by the nmr spectrum.

출처 및 근거

ORD 기록: ord-db0937ad39704dfc8cd2ef564298ef68
출처 데이터셋: uspto-grants-1995_08
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05446189

반응 노트

불러오는 중…