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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 1758199생성일: 2026년 10월 27일

2,2'-((1-Methylethylidene)bis(cyclohexane-4,1-diyloxymethylene))bisoxirane → 2,2-Bis{4-[2-hydroxy-3-(7,7,9,9-tetramethyl-1,4-dioxa-8-azaspiro[4.5]dec-8-yl)propoxy]cyclohexyl}propane

https://huagongshe.com/reaction/1758199

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참여 물질

역할이름HCID투입량
반응물2,2'-((1-Methylethylidene)bis(cyclohexane-4,1-diyloxymethylene))bisoxiraneHCID 114514—
반응물7,7,9,9-Tetramethyl-1,4-dioxa-8-azaspiro[4.5]decaneHCID 567045—
생성물2,2-Bis{4-[2-hydroxy-3-(7,7,9,9-tetramethyl-1,4-dioxa-8-azaspiro[4.5]dec-8-yl)propoxy]cyclohexyl}propaneHCID 20510600—

반응 조건

온도120 °C

반응 단계

A mixture of 8.8 g of 7,7,9,9-tetramethyl-1,4-dioxa-8-azaspiro[4.5]decane and 7.0 g of 2,2-bis[4-(2,3-epoxypropoxy)cyclohexyl]propane was heated at 120° C. for 30 hours. After completion of the reaction, the reaction mixture was purified by column chromatography through silica gel eluted with ethyl acetate. The desired Compound No. 207 was obtained in the form of a pale yellow oil which after being kept at ambient temperature, turned to a solid melting at 48°-50° C.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US04371644
출처 데이터셋uspto-grants-1983_02
ORD IDord-fa8fa4af90de4374802425b3daabc20e
출처 메모uspto-grants-1983_02