Boron trifluoride etherate → Dicumyl peroxide

HRID 1758583

반응식

HRID 1758583 반응식
[C:1]([O:10]C)([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)([CH3:3])[CH3:2].B(F)(F)F.CC[O:18]CC.[O-]O.[C:23]1([CH:29]([CH3:31])[CH3:30])[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1>>[C:29]([O:18][O:10][C:1]([C:4]1[CH:5]=[CH:6][CH:7]=[CH:8][CH:9]=1)([CH3:2])[CH3:3])([C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1)([CH3:31])[CH3:30]

참가 물질

4

반응물 3

HCID 8000Boron trifluoride etherateHCID 70289Methyl cumyl etherHCID 53627471Cumen hydroperoxide2회

생성물 1

HCID 6641Dicumyl peroxide수율 99.8%

반응 조건

온도
60 °C

실험 절차

There are loaded into a 100 ml glass flask, 30 grams of methyl cumyl ether (0.2 moles), 0.1 ml of boron trifluoride diethyl etherate and 9 grams of technical cumene hydroperoxide (0.05 moles) having the same composition as that used in Example 1. The mixture is heated to 60° C. with stirring and maintained at a pressure of 200 mmHg. After 30 minutes the conversion of the cumene hydroperoxide is 100% with a yield of 99.8% of dicumyl peroxide.

후처리

  1. customThere are loaded into a 100 ml glass flask
  2. temperaturemaintained at a pressure of 200 mmHg

출처 및 근거

ORD 기록
ord-d44841cc6a594b178f67f248c9e41fbc
출처 데이터셋
uspto-grants-1983_02
특허 번호
US04374279

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