1-[4-(3-Carbomethoxyprop-2-eneoxy)phenyl]propan-2-one → 1-(4-[3-Carbomethoxypropoxy]phenyl)propan-2-one

HRID 1758988노트

반응식

HRID 1758988 반응식
[C:1]([CH:5]=[CH:6][CH2:7][O:8][C:9]1[CH:14]=[CH:13][C:12]([CH2:15][C:16](=[O:18])[CH3:17])=[CH:11][CH:10]=1)([O:3][CH3:4])=[O:2].[H][H]>C(O)C.[Pd]>[C:1]([CH2:5][CH2:6][CH2:7][O:8][C:9]1[CH:10]=[CH:11][C:12]([CH2:15][C:16](=[O:18])[CH3:17])=[CH:13][CH:14]=1)([O:3][CH3:4])=[O:2]

참가 물질

5

반응물 2

HCID 538253751-[4-(3-Carbomethoxyprop-2-eneoxy)phenyl]propan-2-oneHCID 178418361HCID 178418361, 화합물

생성물 1

HCID 130796131-(4-[3-Carbomethoxypropoxy]phenyl)propan-2-one수율 99.2%

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 702Ethanol용매

실험 절차

To a solution of 1-[4-(3-carbomethoxyprop-2-eneoxy)phenyl]propan-2-one (1.1 g) in ethanol (50 ml), was added 10% Pd/C (100 mg) and the mixture hydrogenated at ambient temperature and atmospheric pressure until hydrogen uptake was complete (approx. 10 minutes). The solution was filtered, evaporated to give the title compound (1.1 g) as an oil.

후처리

  1. customhydrogenated at ambient temperature
  2. custom(approx. 10 minutes)
  3. filtrationThe solution was filtered
  4. customevaporated

출처 및 근거

ORD 기록
ord-5fe1d94af7b0417cb1bc3a573dc4aeb7
출처 데이터셋
uspto-grants-1982_07
특허 번호
US04338333

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