Sodium Iodide → Methyl acetylphosphonate

HRID 1759154노트

반응식

HRID 1759154 반응식
[C:1]([P:4](=[O:9])([O:7]C)[O:5][CH3:6])(=[O:3])[CH3:2].[I-].[Na+:11]>CC(C)=O>[C:1]([P:4](=[O:7])([O-:9])[O:5][CH3:6])(=[O:3])[CH3:2].[Na+:11]

참가 물질

4

반응물 2

HCID 5238Sodium IodideHCID 2785315Dimethyl acetylphosphonate

생성물 1

HCID 23674726Methyl acetylphosphonate

시약·촉매·용매 1

HCID 180Acetone용매

실험 절차

Dimethyl acetylphosphonate (10 g, 0.066 mol) and sodium iodide (15 g, 0.1 mol) were dissolved in acetone (80 ml) and the solution was stirred and refluxed for 6 hours. After cooling, the precipitated solid was filtered off, washed with acetone and ether and then air dried. Yield=9.5 g, m.p. decomp >170°. The NMR spectrum was consistent with the proposed structure.

후처리

  1. temperaturerefluxed for 6 hours
  2. temperatureAfter cooling
  3. filtrationthe precipitated solid was filtered off
  4. washwashed with acetone and ether
  5. customair dried
  6. customm.p. decomp >170°

출처 및 근거

ORD 기록
ord-ab309c2de80d44e996ba08a004182480
출처 데이터셋
uspto-grants-1982_07
특허 번호
US04339443

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