1,2-Dichloroethane → N-(1-methylethyl)-3-(4-chlorophenyl)-2-oxiranecarboxamide

HRID 1759520

반응식

HRID 1759520 반응식
[CH3:1][CH:2]([NH:4][C:5]([C:7](=O)C=CC1C=CC(Cl)=CC=1)=[O:6])[CH3:3].Cl[C:19]1[CH:24]=[CH:23][CH:22]=[C:21]([C:25]([O:27]O)=O)[CH:20]=1.S(C1C(C)=CC(O)=C(C(C)(C)C)C=1)C1C(C)=CC(O)=C(C(C)(C)C)C=1.C(Cl)C[Cl:56]>>[CH3:1][CH:2]([NH:4][C:5]([CH:7]1[CH:25]([C:21]2[CH:20]=[CH:19][C:24]([Cl:56])=[CH:23][CH:22]=2)[O:27]1)=[O:6])[CH3:3]

참가 물질

5

반응물 4

HCID 111,2-DichloroethaneHCID 7308SantonoxHCID 70297m-Chloroperbenzoic acidHCID 53721062N-(1-methylethyl)-4-chlorocinnamoylcarboxamide

생성물 1

HCID 13041336N-(1-methylethyl)-3-(4-chlorophenyl)-2-oxiranecarboxamide

실험 절차

This compound was prepared from N-(1-methylethyl)-4-chlorocinnamoylcarboxamide (18.3 g.), m-chloroperbenzoic acid (19.4 g.), 4,4'-thiobis(6-tert-butyl-m-cresol) (0.3 g.), and ethylene dichloride (250 ml.) as described in Example 7, and purified by recrystallization from ether. The compound melted at 139°-141°, and weighed 11.7 g. The analytical sample which was obtained by another recrystallization from ether melted at 143°-145°.

후처리

  1. custompurified by recrystallization from ether
  2. customThe analytical sample which was obtained by another recrystallization from ether melted at 143°-145°

출처 및 근거

ORD 기록
ord-b320f5c28d44406384b0a8cd6a627737
출처 데이터셋
uspto-grants-1982_07
특허 번호
US04341718

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