Santonox → N-(1-methylethyl)-3-(3-methoxyphenyl)-2-oxiranecarboxamide

HRID 1759521

반응식

HRID 1759521 반응식
[CH3:1][CH:2]([NH:4][C:5]([C:7](=O)C=CC1C=CC=C(OC)C=1)=[O:6])[CH3:3].Cl[C:20]1[CH:25]=[CH:24][CH:23]=[C:22]([C:26]([O:28]O)=O)[CH:21]=1.S(C1C(C)=CC(O)=C(C(C)(C)C)C=1)C1C(C)=C[C:34]([OH:41])=C(C(C)(C)C)C=1>C(Cl)CCl>[CH3:1][CH:2]([NH:4][C:5]([CH:7]1[CH:26]([C:22]2[CH:23]=[CH:24][CH:25]=[C:20]([O:41][CH3:34])[CH:21]=2)[O:28]1)=[O:6])[CH3:3]

참가 물질

5

반응물 3

HCID 7308SantonoxHCID 70297m-Chloroperbenzoic acidHCID 54220101N-(1-methylethyl)-3-methoxycinnamoylcarboxamide

생성물 1

HCID 20490547N-(1-methylethyl)-3-(3-methoxyphenyl)-2-oxiranecarboxamide

시약·촉매·용매 1

HCID 111,2-Dichloroethane용매

실험 절차

This compound was prepared from N-(1-methylethyl)-3-methoxycinnamoylcarboxamide (43.9 g.), m-chloroperbenzoic acid (46 g.), 4,4'-thiobis(6-tert-butyl-m-cresol) (0.6 g.), and ethylene dichloride (500 ml.) as described in Example 7. The compound obtained as an oil was used directly in the subsequent reaction.

후처리

  1. customThe compound obtained as an oil
  2. customwas used directly in the subsequent reaction

출처 및 근거

ORD 기록
ord-52273c1409cf476cafcc5281fecb1265
출처 데이터셋
uspto-grants-1982_07
특허 번호
US04341718

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