Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
6-Ethylchrysene → 12-Ethyl-6-chrysenecarbaldehyde
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 6-Ethylchrysene | HCID 75951 | — |
| 반응물 | 6-Chrysenecarbaldehyde | HCID 12438774 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | 12-Ethyl-6-chrysenecarbaldehyde | HCID 13375390 | 76% |
반응 단계
6-Ethylchrysene (Cambridge Chemical, Inc., 60 g, 0.234 mol) was formylated according to the procedure outlined in 1A, except that CH2Cl2 ( 1 L) was used as the reaction solvent. The crude material was chromatographed on a plug of SiO2 (1 kg) using PhCH3 as the eluting solvent, afforded 50.38 g (76%) of 12-ethyl-6-chrysenecarbaldehyde mp 138°-139°, (C,H).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04829090 |
| 출처 데이터셋 | uspto-grants-1989_05 |
| ORD ID | ord-408512b0db114ddc98def94b327038ee |
| 출처 메모 | uspto-grants-1989_05 |