1-(2,6-Dibromophenyl)thiourea → 2,6-Dibromophenyl isothiocyanate
반응식
[Br:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([Br:8])[C:3]=1[NH:9][C:10](N)=[S:11]>ClC1C=CC=CC=1>[Br:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([Br:8])[C:3]=1[N:9]=[C:10]=[S:11]참가 물질
3
실험 절차
A suspension of 101 g. (0.326 mole) of 1-(2,6-dibromophenyl)thiourea in 1 l. of chlorobenzene was stirred and refluxed 20 hours, and the resulting solution was filtered and evaporated. The tan solid obtained was triturated with boiling petroleum ether and filtered. On cooling, the filtrate deposited 63.4 g. of yellow needles of 2,6-dibromophenylisothiocyanate, m.p. 63°-65°. A portion was recrystallized from ether-petroleum ether to give the analytical sample, m.p. 65°-66°.
후처리
- additionA suspension of 101 g
- temperaturerefluxed 20 hours
- filtrationthe resulting solution was filtered
- customevaporated
- customThe tan solid obtained
- customwas triturated with boiling petroleum ether
- filtrationfiltered
- temperatureOn cooling
- customA portion was recrystallized from ether-petroleum ether
- customto give the analytical sample, m.p. 65°-66°
출처 및 근거
- ORD 기록
- ord-2d56024912db4ea4830dc14a27e4d5b7
- 출처 데이터셋
- uspto-grants-1978_09
- 특허 번호
- US04113776
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