2-Naphthalenesulfonyl chloride → Naphthalene-2-sulfonyl fluoride

반응식

[CH:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][C:2]=1[S:11](Cl)(=[O:13])=[O:12].[F-:15].[K+]>>[CH:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][C:2]=1[S:11]([F:15])(=[O:13])=[O:12]

참가 물질

반응물 2

HCID 71252-Naphthalenesulfonyl chloride

HCID 522689Potassium Fluoride

생성물 1

HCID 12409712Naphthalene-2-sulfonyl fluoride수율 92%

실험 절차

2-Naphthalenesulfonyl fluoride was prepared from 2-naphthalenesulfonyl chloride and potassium fluoride as described in Example 1. A product with mp 85°-86° C (literature 86°-88° C; W. Davies and J. H. Dick, J. Chem. Soc., 2104, 1931) was obtained in 92% yield. The chemical analysis NMR and IR spectra were in agreement with the assigned structure.

후처리

customA product with mp 85°-86° C (literature 86°-88° C; W. Davies and J. H. Dick, J. Chem. Soc., 2104, 1931) was obtained in 92% yield

출처 및 근거

ORD 기록: ord-70bd6a2cffbb489fbdf41b29989cd091
출처 데이터셋: uspto-grants-1978_09
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04115059

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