3-Methyl-1-pentanol → 3-Methyl-1-pentyl methanesulfonate

HRID 1764852

반응식

[CH3:1][CH:2]([CH2:6][CH3:7])[CH2:3][CH2:4][OH:5].[CH3:8][S:9](Cl)(=[O:11])=[O:10]>>[CH3:8][S:9]([O:5][CH2:4][CH2:3][CH:2]([CH3:1])[CH2:6][CH3:7])(=[O:11])=[O:10]

참가 물질

반응물 2

HCID 115083-Methyl-1-pentanol

HCID 31297Methanesulfonyl chloride

생성물 1

HCID 227359043-Methyl-1-pentyl methanesulfonate

실험 절차

The title compound was prepared by following the general procedure of Example 43 for mesylation as a colorless oil (384 mg, 67%) from 3-methyl-1-pentanol (300 mg, 2.90 mmol) and methanesulfonyl chloride (500 mg, 4.40 mmol). 1H NMR (CDCl3, 300 MHz) δ0.86-0.95 (m, 6H), 1.15-1.25 (m, 1H), 1.33-1.42 (m, 1H), 1.51-1.60 (m, 2H), 1.76-1.84 (m, 1H), 3.00 (s, 3H), 4.23-4.31 (m, 2H) ppm.

출처 및 근거

ORD 기록: ord-412e83c2e4a3445eb4c0f4ee21d70ae4
출처 데이터셋: uspto-grants-2007_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: USRE039679E1

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