Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Ammonia → 2-Nitrophenyl phenyl ether
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Ammonia | HCID 222 | — |
| 반응물 | 1-Chloro-2-nitrobenzene | HCID 6945 | — |
| 반응물 | Phenolate Sodium | HCID 4445035 | — |
| 생성물 | 2-Nitrophenyl phenyl ether | HCID 16661 | 93.9% |
반응 단계
A steel autoclave was filled with 157.6 g of o-chloronitrobenzene and 116.1 g of sodium phenolate. At room temperature, 150 g of liquid ammonia were pumped into the vessel, the mixture was heated to 600 with stirring for 15 hours and subsequently cooled. Removal of the ammonia by distillation and workup of the distillation residue gave 202 g of 2-nitrodiphenyl ether (94% of the theoretical yield), 98.5% pure.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05382686 |
| 출처 데이터셋 | uspto-grants-1995_01 |
| ORD ID | ord-26fcceed456e444982cc43b30c71f271 |
| 출처 메모 | uspto-grants-1995_01 |