Glyoxal, phenyl-, hydrate → 3-(Methylthio)-5-phenyl-1,2,4-triazine

HRID 1771290노트

반응식

[NH:1]([C:3]([S:5][CH3:6])=[NH:4])[NH2:2].O.[C:8]1([C:14]([CH:16]=O)=O)[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1>>[CH3:6][S:5][C:3]1[N:1]=[N:2][CH:16]=[C:14]([C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[N:4]=1

참가 물질

반응물 2

HCID 12215922Glyoxal, phenyl-, hydrate

HCID 178504051Methyl hydrazinecarbimidothioate

생성물 1

HCID 985413-(Methylthio)-5-phenyl-1,2,4-triazine수율 73.2%

실험 절차

3-(Methylsulfanyl)-5-phenyl-1,2,4-triazine (2.93 g, 73%) was prepared from methyl hydrazinecarbimidothioate (2.07 g, 19.7 mmol) and phenylglyoxal monohydrate (2.89 g, 19.7 mmol) according to the general procedure of Preparation 2.

후처리

customaccording to the general procedure of Preparation 2

출처 및 근거

ORD 기록: ord-1f4678adfd4845d08fa001dbeb60a397
출처 데이터셋: uspto-grants-2016_02
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US09249130B2

반응 노트

불러오는 중…