Cyclopropanecarbonyl chloride → HCID 136242918, 화합물
반응식
[F:1]C1C=C(C(OC)=O)C2C3C(=O)CNCC=3NC=2C=1.C1(C(Cl)=O)CC1.[CH:26]1([C:29]([N:31]2[CH2:43][C:42]3[NH:41][C:40]4[CH:39]=[CH:38][CH:37]=[C:36]5[C:44](=[O:47])[NH:45][N:46]=[C:33]([C:34]=3[C:35]=45)[CH2:32]2)=[O:30])[CH2:28][CH2:27]1>>[CH:26]1([C:29]([N:31]2[CH2:43][C:42]3[NH:41][C:40]4[CH:39]=[C:38]([F:1])[CH:37]=[C:36]5[C:44](=[O:47])[NH:45][N:46]=[C:33]([C:34]=3[C:35]=45)[CH2:32]2)=[O:30])[CH2:27][CH2:28]1참가 물질
4
실험 절차
Compound 49 was prepared from methyl 7-fluoro-4-oxo-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-5-carboxylate and cyclopropanecarbonyl chloride according to the procedures similar to those for Compound 47. 1H NMR (DMSO-d6) δ 9.64 (s, 1H), 6.80-7.08 (m, 2H), 4.95 (s, 1H), 4.74 (s, 1H), 4.40 (s, 1H), 4.20 (s, 1H), 2.03-2.07 (m, 1H), and 0.75 (s, 4H). MS (ESI) m/e [M+1]+ 313.
출처 및 근거
- ORD 기록
- ord-2fd21e51a5e04c0e95c731ad20230948
- 출처 데이터셋