Triethylamine → 3-Nitrooxy-propyl 5-nitrooxy-hexanoate
반응식
[N+:1]([O:4][CH2:5][CH2:6][CH2:7][OH:8])([O-:3])=[O:2].[CH2:9](N(CC)CC)C.[N+:16]([O:19][CH2:20][CH2:21][CH2:22][CH2:23][C:24](Cl)=[O:25])([O-:18])=[O:17]>C(OCC)C>[N+:16]([O:19][CH:20]([CH3:9])[CH2:21][CH2:22][CH2:23][C:24]([O:8][CH2:7][CH2:6][CH2:5][O:4][N+:1]([O-:3])=[O:2])=[O:25])([O-:18])=[O:17]참가 물질
5
실험 절차
20 mmol 3-Nitrooxypropanol dissolved in 10 ml Diethylether and 20 mmol Triethylamine were cooled to 0° C. 18.2 mmol 5-nitrooxypentoylchlorid were dropped over a period of 5 min at 0 to 5° C. After stirring over night without cooling, the reaction mixture was extracted with 1N HCl, twice with water, washed with brine, dried over Na2SO4 and the solvent was removed in vacuo.
후처리
- temperaturewithout cooling
- extractionthe reaction mixture was extracted with 1N HCl, twice with water
- washwashed with brine
- dry with materialdried over Na2SO4
- customthe solvent was removed in vacuo
출처 및 근거
- ORD 기록
- ord-e5e42d10eb7045f9a12bc42b292b08fb
- 출처 데이터셋
- uspto-grants-2016_02
- 특허 번호
- US09266814B2
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