Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Lithium Hydroxide → (R)-3-Benzylsulfanyl-2-hydroxy-propionic acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Lithium Hydroxide | HCID 3939 | — |
| 반응물 | (R)-3-Benzylsulfanyl-2-hydroxy-propionic acid methyl ester | HCID 59639322 | — |
| 생성물 | (R)-3-Benzylsulfanyl-2-hydroxy-propionic acid | HCID 10059030 | 46% |
반응 단계
This reaction was performed as previously described by Deechongkit, S.; You, S.-L.; Kelly, J. W. Org. Lett. 2004, 6, 497, using (R)-3-Benzylsulfanyl-2-hydroxy-propionic acid methyl ester 110b and lithium hydroxide. (R)-3-Benzylsulfanyl-2-hydroxy-propionic acid 110c (3.08 g, 14.51 mmol, 46%) was isolated as a viscous oil: MS calcd. for C10H12O3S (M+Na+) 235.1, found 235.3.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07501408B2 |
| 출처 데이터셋 | uspto-grants-2009_03 |
| ORD ID | ord-da02151b449d42cbbe103aa172662fa2 |
| 출처 메모 | uspto-grants-2009_03 |