참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Vinyl Acetate | HCID 7904 | — |
| 반응물 | Triethylene Glycol | HCID 8172 | — |
| 반응물 | Sodium Acetate | HCID 517045 | — |
| 반응물 | Ethanol, 2-(2-(2-(ethenyloxy)ethoxy)ethoxy)- | HCID 575880 | — |
| 반응물 | Triethylene glycol divinyl ether | HCID 3033992 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | Triethylene glycol monovinyl ether monoacetate | HCID 22034547 | — |
반응 단계
To a mixture of di-μ-chlorobis(1,5-cyclooctadiene)diiridium(I) [Ir(cod)Cl]2 (0.01 mmol) and sodium acetate (1.2 mmol) in toluene (2.0 ml),triethylene glycol (1 mmol) and vinyl acetate (4 mmol) were added, followed by stirring at 100° C. in an atmosphere of argon gas for 6 hours. The reaction mixture was analyzed by gas chromatography to find that triethylene glycol divinyl ether, triethylene glycol monovinyl ether, and triethylene glycol monovinyl ether monoacetate were produced in yields of 63%, 3%, and 18%, respectively, with a conversion from triethylene glycol of 100%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US07074970B2 |
|---|
| 출처 데이터셋 | uspto-grants-2006_07 |
|---|
| ORD ID | ord-23d6d4ffa44348848a0b664c32a65c64 |
|---|
| 출처 메모 | uspto-grants-2006_07 |
|---|
