Phenylacetylene → Copper (I) phenylacetylide

HRID 1796955노트

반응식

HRID 1796955 반응식
[C:1]1([C:7]#[CH:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Cu:9](I)I>C(O)C.[NH4+].[OH-].O>[C-:8]#[C:7][C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Cu+:9]

참가 물질

6

반응물 2

HCID 10821PhenylacetyleneHCID 83717Copper iodide

생성물 1

HCID 4478696Copper (I) phenylacetylide

시약·촉매·용매 3

HCID 702Ethanol용매HCID 962Water용매HCID 14923Ammonium Hydroxide용매

실험 절차

To a solution of 10.7 g of phenylacetylene in 500 ml of absolute ethanol was added a solution of 20 g of copper iodide in 250 ml of conc. NH4OH and 100 ml of water. The solution was stirred 30 minutes and then filtered. The solid that was collected was washed with water, 95% aq. Ethanol and then ether. The solid was then collected and dried under vacuum to provide the title compound as a bright yellow solid.

후처리

  1. filtrationfiltered
  2. customThe solid that was collected
  3. washwas washed with water, 95% aq. Ethanol
  4. customThe solid was then collected
  5. customdried under vacuum

출처 및 근거

ORD 기록
ord-bc280e876c9a4d4082b16e500a23e038
출처 데이터셋
uspto-grants-2006_04
특허 번호
US07034026B2

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