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(E)-(2S)-2-Amino-5-phenyl-hex-4-en-1-ol → (2S)-2-Amino-5-phenyl-hexan-1-ol

HRID 1807900
노트
인쇄 미리보기

반응식

HRID 1807900 반응식
[NH2:1][C@@H:2]([CH2:5]/[CH:6]=[C:7](/[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)\[CH3:8])[CH2:3][OH:4]>CO.[Pd]>[NH2:1][C@@H:2]([CH2:5][CH2:6][CH:7]([C:9]1[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=1)[CH3:8])[CH2:3][OH:4]
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

4

반응물 1

HCID 67177671(E)-(2S)-2-Amino-5-phenyl-hex-4-en-1-ol

생성물 1

HCID 67177481(2S)-2-Amino-5-phenyl-hexan-1-ol

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 887Methanol용매

실험 절차

To a solution of (E)-(2S)-2-amino-5-phenyl-hex-4-en-1-ol (180 mg) in methanol (25 ml) at room temperature was added 10% palladium on charcoal (50 mg). The mixture was stirred under an atmosphere of hydrogen (1 atm) at room temperature for 2 h. The catalyst was removed by filtration and the filtrate was concentrated in vacuo to yield a colourless oil, (160 mg, 88%); MS (ISP): 194.3 ([M+H]+).

후처리

  1. customThe catalyst was removed by filtration
  2. concentrationthe filtrate was concentrated in vacuo
  3. customto yield a colourless oil, (160 mg, 88%)

출처 및 근거

ORD 기록
ord-ea8884ce71f44856aed29b2e190018e5
출처 데이터셋
uspto-grants-2013_01
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US08357712B2

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