Potassium Carbonate → Ethyl 4-(benzyloxy)-3-hydroxybenzoate

HRID 1810918노트

반응식

HRID 1810918 반응식
[CH2:1]([O:3][C:4](=[O:23])[C:5]1[CH:10]=[CH:9][C:8]([O:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[C:7]([O:19]C(=O)C)[CH:6]=1)[CH3:2].C(=O)([O-])[O-].[K+].[K+]>CO>[CH2:1]([O:3][C:4](=[O:23])[C:5]1[CH:10]=[CH:9][C:8]([O:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[C:7]([OH:19])[CH:6]=1)[CH3:2]

참가 물질

4

반응물 2

HCID 11430Potassium CarbonateHCID 67170201HCID 67170201, 화합물

생성물 1

HCID 11311797Ethyl 4-(benzyloxy)-3-hydroxybenzoate

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

The compound of step 1 (10 g, 31.8 mmol) was dissolved in methanol, potassium carbonate (88 mg, 0.636 mmol) was added and the mixture was stirred for 2 h under reflux. After evaporation to dryness, the residue was used without further purification in the subsequent step.

후처리

  1. temperatureunder reflux
  2. customAfter evaporation to dryness
  3. customthe residue was used without further purification in the subsequent step

출처 및 근거

ORD 기록
ord-847ccc0412f24323a43d8dcb4df6878b
출처 데이터셋
uspto-grants-2013_01
특허 번호
US08362073B2

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