참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Styrene | HCID 7501 | — |
| 반응물 | Abietic Acid | HCID 10569 | — |
| 반응물 | Potassium Hydroxide | HCID 14797 | — |
| 반응물 | Tert-dodecanethiol | HCID 32793 | — |
| 반응물 | Potassium Phosphate, Tribasic | HCID 62657 | — |
| 반응물 | CID 21225536 | HCID 21225536 | — |
| 반응물 | Sodium;formaldehyde;naphthalene-1-sulfonate | HCID 23688955 | — |
| 반응물 | 1-(4-Phenylbut-3-enyl)pyrrolidine | HCID 67206089 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | Styrene/butadiene pyrrolidinoethyl styrene | HCID 86591653 | — |
반응 단계
In this experiment, an emulsion a styrene/butadiene/pyrrolidinoethyl styrene (PES) terpolymer was prepared. In the procedure used, 7.29 lbs. of soft water, 4.76 grams of sodium naphthalenesulfonate-formaldehyde dispersant (Daxad 14B from Hampshire Chemical Co., 47.5% active), 7.2 gms. of tripotassium phosphate, 140 grams of disproportionated rosin acid (potassium salt, 20% solution in water at pH 9.5), and 532 grams of C14–18 and C16–18 unsaturated fatty acids (potassium salt, 10% solution in water at pH 9.5) were charged into a 2-gallon stainless steel reactor. Prior to charging to the reactor, the pH of the solution was adjusted to 10.2–10.8 by the addition of a 10% aqueous potassium hydroxide solution. Then, 100 grams of soft water, 0.32 grams of ethylenediaminetetraacetic acid/ferric sodium complex (Akzo Nobel Chemicals Co.) and 1.08 grams of sodium formaldehyde sulfoxylate were added. Then, 580 grams of styrene, 22.5 grams of PES (92% purity), and 4.5 grams of tert-dodecylmercaptan were added.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US07041761B2 |
|---|
| 출처 데이터셋 | uspto-grants-2006_05 |
|---|
| ORD ID | ord-93873db830ef40d78326c2925ffbfa3f |
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| 출처 메모 | uspto-grants-2006_05 |
|---|
