4-Chlorobenzaldehyde → 4-[2-(4-Chloro-phenyl)-vinyl]-1-nitro-benzene

HRID 1827436노트

반응식

HRID 1827436 반응식
C(OP([CH2:9][C:10]1[CH:15]=[CH:14][C:13]([N+:16]([O-:18])=[O:17])=[CH:12][CH:11]=1)(=O)OCC)C.[Cl:19][C:20]1[CH:27]=[CH:26][C:23]([CH:24]=O)=[CH:22][CH:21]=1>>[Cl:19][C:20]1[CH:27]=[CH:26][C:23]([CH:24]=[CH:9][C:10]2[CH:11]=[CH:12][C:13]([N+:16]([O-:18])=[O:17])=[CH:14][CH:15]=2)=[CH:22][CH:21]=1

참가 물질

3

반응물 2

HCID 77264-ChlorobenzaldehydeHCID 256065Diethyl 4-nitrobenzylphosphonate

생성물 1

HCID 1554154-[2-(4-Chloro-phenyl)-vinyl]-1-nitro-benzene수율 95%

실험 절차

Prepared in analogy to example 56b) from (4-nitro-benzyl)-phosphonic acid diethyl ester and 4-chloro-benzaldehyde. Yellow solid. Yield=95%. MS: m/e=259.1 (M+).

출처 및 근거

ORD 기록
ord-6f871d7f569c4c3fbd4f9a75da0ce395
출처 데이터셋
uspto-grants-2006_05
특허 번호
US07053245B2

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