3,5-Dinitrosalicylic acid → 2-Nitrophenol

반응식

[N+:1]([C:4]1[CH:12]=[C:11]([N+]([O-])=O)[CH:10]=[C:6](C(O)=O)[C:5]=1[OH:16])([O-:3])=[O:2].C1C=CC2N(O)N=NC=2C=1.CC(C)N=C=NC(C)C>>[N+:1]([C:4]1[CH:12]=[CH:11][CH:10]=[CH:6][C:5]=1[OH:16])([O-:3])=[O:2]

참가 물질

반응물 3

HCID 118733,5-Dinitrosalicylic acid

HCID 12734Diisopropylcarbodiimide

HCID 757711-Hydroxybenzotriazole

생성물 1

HCID 69472-Nitrophenol

실험 절차

This material was prepared from 3,5-dinitrosalicylic acid (1d) (1 g, 4.4 mmol), HOBt (1 g, 7.4 mmol), DIC (1,3-diisopropylcarodiimide, 1 mL, 6.4 mmol), and an amino tantagel resin (1 g, 0.45 mmol) using a procedure similar to polystyrene resin (PS-2a).

출처 및 근거

ORD 기록: ord-03d305d91952485eb0d7d6b0f01561a6
출처 데이터셋: uspto-grants-2006_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07060752B2

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