Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Trifluoroacetic acid → (4R)-4,8-Dimethylnonanoic acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Trifluoroacetic acid | HCID 6422 | — |
| 반응물 | tert-butyl (4R)-4,8-dimethylnonanoate | HCID 71406104 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | (4R)-4,8-Dimethylnonanoic acid | HCID 71351570 | — |
반응 단계
(4R)-4,8-dimethyl nonanoic acid t-butyl ester in 25 mL CH2Cl2 at 0° C. was treated with TFA (6 mL). The mixture was allowed to reach ambient temperature and stir overnight. The solvent was removed by rotary evaporation, and the mixture was purified by silica gel chromatography (95/5 hexane/EtOAc) to give 0.962 g (4R)-4,8-dimethyl nonanoic acid. m/z 185 (M−).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07064147B2 |
| 출처 데이터셋 | uspto-grants-2006_06 |
| ORD ID | ord-fc3f4df650e14fc6ac4203787404fd1e |
| 출처 메모 | uspto-grants-2006_06 |