Carbamic chloride, N-methyl-N-phenyl- → Methyl-phenyl-carbamic Acid 4-(4-nitro-phenoxy)-phenyl Ester

반응식

[N+:1]([C:4]1[CH:17]=[CH:16][C:7]([O:8][C:9]2[CH:14]=[CH:13][C:12]([OH:15])=[CH:11][CH:10]=2)=[CH:6][CH:5]=1)([O-:3])=[O:2].[CH3:18][N:19]([C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1)[C:20](Cl)=[O:21]>>[N+:1]([C:4]1[CH:17]=[CH:16][C:7]([O:8][C:9]2[CH:14]=[CH:13][C:12]([O:15][C:20](=[O:21])[N:19]([CH3:18])[C:23]3[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=3)=[CH:11][CH:10]=2)=[CH:6][CH:5]=1)([O-:3])=[O:2]

참가 물질

반응물 2

HCID 77969Carbamic chloride, N-methyl-N-phenyl-

HCID 1524504-(4-Nitrophenoxy)phenol

생성물 1

HCID 10215649Methyl-phenyl-carbamic Acid 4-(4-nitro-phenoxy)-phenyl Ester

실험 절차

The title compound was prepared from 4-(4-nitro-phenoxy)-phenol and N-methyl-N-phenylcarbamoyl chloride. The crude product was subjected to preparative HPLC (71%, white crystals). HPLC-MS m/z=365.0 (M+1), Rt: 4.83 min.

출처 및 근거

ORD 기록: ord-6174b3c5bbff46009a0a5af7620521e4
출처 데이터셋: uspto-grants-2006_06
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07067517B2

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