Acrylic Acid → 3-(Trichlorogermyl)propanoic acid
반응식
[Cl:1][GeH:2]([Cl:4])[Cl:3].[C:5]([OH:9])(=[O:8])[CH:6]=[CH2:7]>CCOCC>[Cl:1][Ge:2]([Cl:4])([Cl:3])[CH2:7][CH2:6][C:5]([OH:9])=[O:8]참가 물질
4
실험 절차
To a magnetically stirred solution of 18 g (0.1 mole) of trichlorogermane in 30 ml of anhydrous ether was added dropwise with a solution of 7.2g (0.1 mole) of acrylic acid in 20 ml of ether at -30°. Then, the mixture was allowed to stand at room temperature for 2 hrs. Evaporation of the solvent left a solid, which was recrystallized from n-hexane to give 22.5 g (89.3% yield) of white needles, mp 84°~85°. Lit. (V. F. Mironov, E. M. Berliner, and T. K. Gar, Zh. Obshch, Khim., 37, 962 (1967) reports mp 83°~85° for this compound.
후처리
- customEvaporation of the solvent
- waitleft a solid, which
- customwas recrystallized from n-hexane
출처 및 근거
- ORD 기록
- ord-9d0ad41cd407419e80a22a66f4978f7c
- 출처 데이터셋
- uspto-grants-1978_01
- 특허 번호
- US04066678
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