Acetic Acid → HCID 21317539, 화합물

HRID 1833454노트

반응식

HRID 1833454 반응식
[Cl:1][CH2:2][CH2:3][S:4][CH:5]([CH2:17][CH2:18][CH2:19][CH:20]([O:26][C:27](=[O:29])[CH3:28])[CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([O:14][CH2:15][CH3:16])=[O:13].OO.[OH2:32].C(O)(=[O:35])C>CCOCC>[Cl:1][CH2:2][CH2:3][S:4]([CH:5]([CH2:17][CH2:18][CH2:19][CH:20]([O:26][C:27](=[O:29])[CH3:28])[CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([O:14][CH2:15][CH3:16])=[O:13])(=[O:35])=[O:32]

참가 물질

6

반응물 4

HCID 176Acetic AcidHCID 784Hydrogen PeroxideHCID 962WaterHCID 21317532Ethyl 8-(2-chloroethylthio)-12-acetoxyheptadecanoate

생성물 1

HCID 21317539HCID 21317539, 화합물

시약·촉매·용매 1

HCID 3283Diethyl Ether용매

실험 절차

A solution of ethyl 8-(2-chloroethylthio)-12-acetoxyheptadecanoate (45.1 g., 0.1 mole) and 30% aqueous hydrogen peroxide (50 ml.) in acetic acid (225 ml.) is allowed to stand 20 hours at 25° C. The solution is diluted with 600 ml. of water. The oily product is taken up in ether, washed with dilute sodium bicarbonate solution and four portions of water and dried over sodium sulfate. Evaporation of the ether in vacuo leaves the title compound as a light yellow viscous oil.

후처리

  1. additionThe solution is diluted with 600 ml
  2. washwashed with dilute sodium bicarbonate solution and four portions of water
  3. dry with materialdried over sodium sulfate
  4. customEvaporation of the ether in vacuo

출처 및 근거

ORD 기록
ord-baa1316a04764c80889221a54e97d61f
출처 데이터셋
uspto-grants-1978_01
특허 번호
US04066675

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