1-Naphthol → N-Butylnaphthalen-1-amine

HRID 1833969노트

반응식

HRID 1833969 반응식
[C:1]1(O)[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][CH:2]=1.P(OC1C=CC=CC=1)(OC1C=CC=CC=1)OC1C=CC=CC=1.[CH2:34]([NH2:38])[CH2:35][CH2:36][CH3:37]>>[CH2:34]([NH:38][C:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][CH:2]=1)[CH2:35][CH2:36][CH3:37]

참가 물질

4

반응물 3

HCID 70051-NaphtholHCID 7540Triphenyl phosphiteHCID 8007Butylamine

생성물 1

HCID 221510N-Butylnaphthalen-1-amine수율 87%

실험 절차

288 parts of α-naphthol, 10 parts of triphenyl phosphite and 160 parts of n-butylamine are heated for 20 hours at 220° C in a pressure autoclave, whilst stirring. The further working up is carried out as described in Example 3. 346 parts of n-butyl-α-naphthylamine, boiling at 160° - 162° C/18 mm Hg, are obtained, corresponding to a yield of 87% of theory.

출처 및 근거

ORD 기록
ord-d2255fb09c704e31a021bb4cbf037597
출처 데이터셋
uspto-grants-1978_01
특허 번호
US04067903

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