Ammonia → 1-Aminooctan-2-ol

HRID 1834665

반응식

HRID 1834665 반응식
[NH3:1].C(O)C.[O:5]1[CH:7]([CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13])[CH2:6]1>O>[OH:5][CH:7]([CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13])[CH2:6][NH2:1]

참가 물질

5

반응물 3

HCID 222Ammonia2회HCID 702EthanolHCID 181262-Hexyloxirane

생성물 1

HCID 3450531-Aminooctan-2-ol수율 77.1%

시약·촉매·용매 1

HCID 962Water용매

실험 절차

One-thousand one-hundred grams of ammonia gas was introduced into a mixture of 6 liters of ethanol and 1 liter of water and within 30 minutes there were dropped in at room temperature 320 grams of 1,2-epoxyoctane. The mixture was left at room temperature for 70 minutes under gentle stirring, then the solvent and excess ammonia drawn off and the residue rectified in a vacuu. There were obtained 277.6 grams (77.1% of theory) of 2-hydroxyoctyl amine having a boiling point (0.4 mm Hg) of 80° C.

출처 및 근거

ORD 기록
ord-6c487342f67e4a08af32f7323dc850a7
출처 데이터셋
uspto-grants-1978_01
특허 번호
US04070531

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