참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | 3-(3-Nitro-phenyl)-acrylonitrile | HCID 55669 | — |
| 촉매 | Chlorotris(triphenylphosphine)rhodium(I) | HCID 84599 | — |
| 용매 | Benzene | HCID 241 | — |
| 생성물 | 3-(3-Nitro-phenyl)-propionitrile | HCID 22186098 | — |
반응 단계
There are introduced into a cylinder 3 g of the product obtained in Step 1, 1.59 g of tris(triphenylphosphine)rhodium(I) chloride and 90 ml of benzene. The whole is heated for 5 hours at 40° C. under a hydrogen pressure of 5 bar. The solvent is evaporated off and the residue is purified by chromatography on silica gel using dichloromethane as eluant.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US06784183B2 |
|---|
| 출처 데이터셋 | uspto-grants-2004_08 |
|---|
| ORD ID | ord-85e8aacf647b40d99e6441bc79a44ef9 |
|---|
| 출처 메모 | uspto-grants-2004_08 |
|---|
