참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Benzene | HCID 241 | — |
| 반응물 | Water | HCID 962 | — |
| 반응물 | 2,6-Pyridinedicarbonyl dichloride | HCID 77335 | — |
| 반응물 | Aluminum(III) Chloride | HCID 6451240 | — |
| 생성물 | 2,6-Dibenzoylpyridine | HCID 316656 | 58% |
반응 단계
Aluminium trichloride (5.1 g, 3.18 mmol) was added to a suspension of 2,6-bis(chlorocarbonyl)pyridine (3.7 g, 18 mmol) in 200 ml of benzene. The reaction mixture was heated to 60° C. and kept at that temperature for 4 h and subsequently for 16 h at room temperature. The mixture was poured into water, the organic layer was separated and evaporated to dryness. The residue was dissolved in CH2Cl2 and filtered. Removal of CH2Cl2 in vacuum yielded 3.0 g (58%) of product.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US06683187B2 |
|---|
| 출처 데이터셋 | uspto-grants-2004_01 |
|---|
| ORD ID | ord-48fbbee0fd4c4da082c56e3bc44acdc8 |
|---|
| 출처 메모 | uspto-grants-2004_01 |
|---|
