Hydrogen Peroxide → 6-hydroxy-4-methylbenzo[d]oxazol-2(3H)-one

HRID 1846417노트

반응식

HRID 1846417 반응식
[CH3:1][C:2]1[C:7]2[NH:8][C:9](=[O:11])[O:10][C:6]=2[CH:5]=[C:4]([O:12]B(O)O)[CH:3]=1.OO>C(O)(=O)C>[OH:12][C:4]1[CH:3]=[C:2]([CH3:1])[C:7]2[NH:8][C:9](=[O:11])[O:10][C:6]=2[CH:5]=1

참가 물질

4

반응물 2

HCID 784Hydrogen PeroxideHCID 669782724-Methyl-2-oxo-2,3-dihydrobenzo[d]oxazol-6-ylboric acid

생성물 1

HCID 669780936-hydroxy-4-methylbenzo[d]oxazol-2(3H)-one

시약·촉매·용매 1

HCID 176Acetic Acid용매

실험 절차

77 mg (0.40 mmol) 4-methyl-2-oxo-2,3-dihydrobenzo[d]oxazol-6-ylboric acid were dissolved in 2.0 mL glacial acetic acid and mixed with 0.20 mL (2.3 mmol) hydrogen peroxide solution (35% in water) and stirred briefly. The reaction mixture was left to stand for 1 h at RT. The precipitate formed was suction filtered, washed with water and dried i. vac.

후처리

  1. waitThe reaction mixture was left
  2. customThe precipitate formed
  3. filtrationfiltered
  4. washwashed with water
  5. customdried i

출처 및 근거

ORD 기록
ord-ae0a62c06edc422f8e8d1e65b131a93d
출처 데이터셋
uspto-grants-2015_02
특허 번호
US08952014B2

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