tert-Butyl (4-aminophenyl)carbamate → HCID 131732467, 화합물

반응식

O([C:9]1[CH:18]=[CH:17][C:16]2[CH2:15][CH2:14][CH2:13][CH2:12][C:11]=2[C:10]=1[N+:19]([O-:21])=[O:20])S(C(F)(F)F)(=O)=O.[C:22]([O:26][C:27](=[O:36])[NH:28][C:29]1[CH:34]=[CH:33][C:32]([NH2:35])=[CH:31][CH:30]=1)([CH3:25])([CH3:24])[CH3:23]>>[N+:19]([C:10]1[C:11]2[CH2:12][CH2:13][CH2:14][CH2:15][C:16]=2[CH:17]=[CH:18][C:9]=1[NH:35][C:32]1[CH:31]=[CH:30][C:29]([NH:28][C:27](=[O:36])[O:26][C:22]([CH3:24])([CH3:23])[CH3:25])=[CH:34][CH:33]=1)([O-:21])=[O:20]

참가 물질

반응물 2

HCID 688611tert-Butyl (4-aminophenyl)carbamate

HCID 86689304HCID 86689304, 화합물

생성물 1

HCID 131732467HCID 131732467, 화합물수율 49%

실험 절차

1-Nitro-5,6,7,8-tetrahydronaphthalen-2-yl triflate (3.25 g, 10 mmol) and tert-butyl(4-aminophenyl)carbamate (2.08 g, 10 mmol) were used in a process similar to Example 1(1) to give the titled compound as a red solid (1.88 g, yield 49%).

출처 및 근거

ORD 기록: ord-70991247abeb4711a986faa64c9ca720
출처 데이터셋: uspto-grants-2015_02
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08962613B2

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